901162
cis-[1,2-Bis(diphenylphosphino)ethane](2-methylphenyl)nickel(II) chloride
≥95%
Synonym(s):
cis-(dppe)Ni(o-tolyl)Cl
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About This Item
Empirical Formula (Hill Notation):
C33H31ClNiP2
CAS Number:
Molecular Weight:
583.69
UNSPSC Code:
12352200
assay
≥95%
form
powder or solid
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni]1(C2=C(C)C=CC=C2)P(C3=CC=CC=C3)(C4=CC=CC=C4)CCP1(C5=CC=CC=C5)C6=CC=CC=C6
Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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