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Merck
CN

901443

Trimethylphosphine solution

90% M in 2-methyltetrahydrofuran, liquid

Synonym(s):

Trimethylphosphane, PMe3, Trimethylphosphorus

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About This Item

Linear Formula:
(CH3)3P
CAS Number:
Molecular Weight:
76.08
UNSPSC Code:
12352128
NACRES:
NA.22
MDL number:
Beilstein/REAXYS Number:
969138
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Product Name

Trimethylphosphine solution, 0.9 M in 2-methyltetrahydrofuran

Quality Level

form

liquid

reaction suitability

reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reaction

concentration

0.9 M in 2-methyltetrahydrofuran

density

0.838 g/mL

functional group

phosphine

SMILES string

CP(C)C

InChI

1S/C3H9P/c1-4(2)3/h1-3H3

InChI key

YWWDBCBWQNCYNR-UHFFFAOYSA-N

Application

Trimethylphosphine is an electron-rich phosphine ligand used in the Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

5.0 °F

flash_point_c

-15 °C

Regulatory Information

监管及禁止进口产品

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Global Trade Item Number

SKUGTIN
901443-25ML04061835531622