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902039

4-Methoxypicolinimidamide hydrochloride

Name: 4-Methoxypicolinimidamide hydrochloride
Brand: ALDRICH

≥95%, powder or solid

Synonym(s):

Weix 2-pyridylcarboxamidine ligand for nickel catalysis

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About This Item

Empirical Formula (Hill Notation):

C₇H₁₀ClN₃O

CAS Number:

1179361-66-0

Molecular Weight:

187.63

UNSPSC Code:

12352101

NACRES:

NA.22

MDL number:

MFCD12755550

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Properties

Product Name

4-Methoxypicolinimidamide hydrochloride, ≥95%

assay

≥95%

form

powder or solid

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

174-176 °C

SMILES string

Cl.N\C(=N/[H])\c1nccc(c1)OC

InChI

1S/C7H9N3O.ClH/c1-11-5-2-3-10-6(4-5)7(8)9;/h2-4H,1H3,(H3,8,9);1H

InChI key

JOUDWIBACXLPIO-UHFFFAOYSA-N

Description

Application

This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.

Other Notes

Coupling of Challenging Heteroaryl Halides with Alkyl Halides via Nickel-Catalyzed Cross-Electrophile Coupling

New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries

Electrochemical Nickel Catalysis for Sp²-Sp³ Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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