904767
[Ru(phen)3]Cl2
≥95%, powder or crystals
Synonym(s):
Dichlorotris(1,10-phenanthroline)ruthenium(II) chloride
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About This Item
Empirical Formula (Hill Notation):
C36H24Cl2N6Ru
CAS Number:
Molecular Weight:
712.59
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Product Name
[Ru(phen)3]Cl2, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
SMILES string
[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]
InChI
1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
InChI key
UWXWBVKIJZGXQL-UHFFFAOYSA-L
Application
[Ru(phen)3]Cl2 is a cyclometalated ruthenium complex that can be used in visible light mediated photocatalytic organic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Jun Chen et al.
Chemical communications (Cambridge, England), 54(50), 6780-6783 (2018-02-06)
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the