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904961

Feng L3-PrPr2

≥95%, powder

Synonym(s):

(2S,2′S)-1,1′-(propane-1,3-diyl)bis(2-((2,6-diisopropylphenyl)carbamoyl)pyrrolidine 1-oxide)

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About This Item

Empirical Formula (Hill Notation):
C37H56N4O4
CAS Number:
945564-85-2
Molecular Weight:
620.86
MDL number:
MFCD32197453
UNSPSC Code:
12161600
NACRES:
NA.22
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Product Name

Feng L3-PrPr2, ≥95%

assay

≥95%

form

powder

mp

154-159 °C

storage temp.

2-8°C

SMILES string

[N+]3([C@H](CCC3)C(=O)Nc4c(cccc4C(C)C)C(C)C)([O-])CCC[N+]1([C@H](CCC1)C(=O)Nc2c(cccc2C(C)C)C(C)C)[O-]

InChI

1S/C37H56N4O4/c1-24(2)28-14-9-15-29(25(3)4)34(28)38-36(42)32-18-11-20-40(32,44)22-13-23-41(45)21-12-19-33(41)37(43)39-35-30(26(5)6)16-10-17-31(35)27(7)8/h9-10,14-17,24-27,32-33H,11-13,18-23H2,1-8H3,(H,38,42)(H,39,43)/t32-,33-,40?,41?/m1/s1

InChI key

GRKRBQGUOZNATH-LENWBBSMSA-N

Application

L3-PrPr2 is a chiral N,N-dioxide ligand developed by the Feng group. In conjunction with a variety of metal salts, this versatile ligand forms and active catalysts complex with application in many different reactions.

Other Notes

Enantioselective Allylation of Ketones Catalyzed by N,N′-Dioxide and Indium(III) Complex

Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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