905313
Rh2(S-TCPTAD)4
powder or crystals
Synonym(s):
Davies dirhodium catalyst
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About This Item
Empirical Formula (Hill Notation):
C80H64Cl16N4O16Rh2
CAS Number:
Molecular Weight:
2110.44
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352101
Product Name
Rh2(S-TCPTAD)4,
form
powder or crystals
Application
This dirhodium catalyst developed by the Davies lab can form C-C bonds at the most accessible tertiary C-H position with control of both regioselectivity and absolute configuration.
Other Notes
Formation of Tertiary Alcohols from the Rhodium-Catalyzed Reactions of Donor/Acceptor Carbenes with Esters
Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds
Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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