90660
Tribenzylamine
≥99.0% (NT)
Synonym(s):
TBA
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About This Item
Linear Formula:
(C6H5CH2)3N
CAS Number:
Molecular Weight:
287.40
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-638-3
Beilstein/REAXYS Number:
2214682
MDL number:
Assay:
≥99.0% (NT)
Form:
powder
assay
≥99.0% (NT)
form
powder
mp
91-94 °C (lit.)
functional group
amine, phenyl
SMILES string
C(N(Cc1ccccc1)Cc2ccccc2)c3ccccc3
InChI
1S/C21H21N/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2
InChI key
MXHTZQSKTCCMFG-UHFFFAOYSA-N
Application
Tribenzylamine (TBA) is a tertiary amine which can be used :
TBA can also undergo debenzylation in the presence of ceric ammonium nitrate (CAN) to form dibenzylamine.
- As a nitrogen group source for the reactions involving C−N bond formation.
- For the synthesis of imine i.e. N−benzylidene benzylamine by aerobic oxidative condensation.
- As an extractant for the separation and determination of Cr(VI) and Cr(III) from wastewater.
TBA can also undergo debenzylation in the presence of ceric ammonium nitrate (CAN) to form dibenzylamine.
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signalword
Warning
hcodes
Hazard Classifications
Skin Sens. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
399.2 °F - closed cup
flash_point_c
204 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Céline Burnier et al.
Talanta, 192, 135-141 (2018-10-24)
Nowadays, Gas Chromatography Mass Spectrometry (GC-MS) is mainly used in forensic sciences but suffers from limitations when the analysed compounds are thermally instable as it is the case for THC-A (Tetrahydrocannabinolic Acid) which is converted into Δ9-THC (Δ9-Tetrahydrocannabinol) that subsequently
Copper-Catalyzed Oxidative Amination of Benzoxazoles via C- H and C- N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources.
Guo S, et al.
Organic Letters, 13(3), 522-525 (2010)
Najat S Khan et al.
The Journal of organic chemistry, 76(5), 1418-1424 (2011-01-29)
A gyroscope-inspired tribenzylamine hemicryptophane provides a vehicle for exploring the structure and properties of multiple p-phenylene rotators within one molecule. The hemicryptophane was synthesized in three steps in good overall yield using mild conditions. Three rotator-forming linkers were cyclized to
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 90660-500G | 04061833247174 |
| 90660-100G | 04061835370016 |