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Merck
CN

907073

PO-T2T

>=99% (HPLC), Mw 909.8 g/mol,

别名:

(1,3,5-三嗪-2,4,6-三基)三(苯-3,1-二基)三(二苯基膦氧化物), 2,4,6-三[3-(二苯基膦氧基)苯基]-1,3,5-三嗪

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关于此项目

经验公式(希尔记法):
C57H42N3O3P3
化学文摘社编号:
分子量:
909.88
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23
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产品名称

PO-T2T, >=99% (HPLC),

grade

sublimed grade (>99% (HPLC))

description

PL-295, 379 nm (in CH2Cl2)

form

solid

mol wt

Mw 909.8 g/mol

color

white

λmax

272 nm in dichloromethane

orbital energy

HOMO -6.8 eV , LUMO -2.8 eV 

storage temp.

15-25°C

SMILES string

[P](=O)(c3cc(ccc3)c4nc(nc(n4)c8cc(ccc8)[P](=O)(c%10ccccc%10)c9ccccc9)c5cc(ccc5)[P](=O)(c7ccccc7)c6ccccc6)(c2ccccc2)c1ccccc1

InChI key

RDVGOMWIWCMKAM-UHFFFAOYSA-N

General description

PO-T2T (≥99% HPLC) is a high-performance organic semiconductor known for its exceptional electron transport properties. With a molecular weight of 909.8 g/mol and a CAS number of 1646906-26-4, this compound is characterized by its ability to facilitate efficient charge transport in organic electronic devices. PO-T2T has been successfully utilized in tandem organic light-emitting diodes (OLEDs) and as a hole-blocking layer in various device architectures. Its unique chemical structure allows it to achieve high external quantum efficiency and excellent device performance, making it a valuable material for researchers and manufacturers in the field of organic electronics.

Application

PO-T2T是有机发光二极管(OLED)中的电子传输/空穴阻挡材料,或有机电子器件中的电子受体材料。

一项在《自然》发表的研究演示了自由基OLED的有效作用,它们通过自旋双线态激子发光,而不是单线态和三线态激子。
双线态激子没有跃迁过程中的自旋禁阻问题,从而避开了长久以来的三线态激子的利用问题。采用发光自由基激子的OLED,最大外量子效率已达到27%(710nm),是目前为止已报道的深红光/近红外光发光二极管(LED)中的最高值。在这种高效的OLED器件中,采用TAPC作为空穴传输层,PO-T2T作为电子传输层,实现选择性地空穴注入HOMO,电子注入SOMO,形成近100%内量子效率的荧光双线激发态。

Features and Benefits

  • High Purity: Assay of ≥99% (HPLC) ensures reliable performance and consistency in applications.
  • Molecular Weight: 909.8 g/mol, facilitating accurate formulation and dosing in various applications.
  • Optical Properties: Exhibits a maximum absorbance at λmax of 272 nm in dichloromethane, enhancing its utility in photonic applications.
  • Stable Performance: The compound is solid at room temperature, making it easy to handle and process.
  • Electron Transport Capabilities: Functions effectively as an electron transport layer (ETL) and hole-blocking material in OLEDs.
  • Versatile Applications: Ideal for use in OLEDs, organic photovoltaics (OPVs), and other organic electronic devices, making it a valuable compound across multiple industries.
  • Enhanced Device Efficiency: The ability to facilitate efficient charge transport improves the performance of OLEDs, contributing to higher brightness and lower power consumption.
  • Innovative Device Architecture: PO-T2T enables the development of tandem OLEDs with excellent efficiencies, demonstrating its potential in advanced organic electronic applications.
  • Research and Development Utility: An excellent candidate for researchers exploring new materials in organic electronics, providing a reliable platform for experimentation and innovation.


存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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