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关于此项目
经验公式(希尔记法):
C57H42N3O3P3
化学文摘社编号:
分子量:
909.88
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23
产品名称
PO-T2T, >=99% (HPLC),
grade
sublimed grade (>99% (HPLC))
description
PL-295, 379 nm (in CH2Cl2)
form
solid
mol wt
Mw 909.8 g/mol
color
white
λmax
272 nm in dichloromethane
orbital energy
HOMO -6.8 eV , LUMO -2.8 eV
storage temp.
15-25°C
SMILES string
[P](=O)(c3cc(ccc3)c4nc(nc(n4)c8cc(ccc8)[P](=O)(c%10ccccc%10)c9ccccc9)c5cc(ccc5)[P](=O)(c7ccccc7)c6ccccc6)(c2ccccc2)c1ccccc1
InChI key
RDVGOMWIWCMKAM-UHFFFAOYSA-N
General description
PO-T2T (≥99% HPLC) is a high-performance organic semiconductor known for its exceptional electron transport properties. With a molecular weight of 909.8 g/mol and a CAS number of 1646906-26-4, this compound is characterized by its ability to facilitate efficient charge transport in organic electronic devices. PO-T2T has been successfully utilized in tandem organic light-emitting diodes (OLEDs) and as a hole-blocking layer in various device architectures. Its unique chemical structure allows it to achieve high external quantum efficiency and excellent device performance, making it a valuable material for researchers and manufacturers in the field of organic electronics.
Application
PO-T2T是有机发光二极管(OLED)中的电子传输/空穴阻挡材料,或有机电子器件中的电子受体材料。
一项在《自然》发表的研究演示了自由基OLED的有效作用,它们通过自旋双线态激子发光,而不是单线态和三线态激子。
双线态激子没有跃迁过程中的自旋禁阻问题,从而避开了长久以来的三线态激子的利用问题。采用发光自由基激子的OLED,最大外量子效率已达到27%(710nm),是目前为止已报道的深红光/近红外光发光二极管(LED)中的最高值。在这种高效的OLED器件中,采用TAPC作为空穴传输层,PO-T2T作为电子传输层,实现选择性地空穴注入HOMO,电子注入SOMO,形成近100%内量子效率的荧光双线激发态。
一项在《自然》发表的研究演示了自由基OLED的有效作用,它们通过自旋双线态激子发光,而不是单线态和三线态激子。
双线态激子没有跃迁过程中的自旋禁阻问题,从而避开了长久以来的三线态激子的利用问题。采用发光自由基激子的OLED,最大外量子效率已达到27%(710nm),是目前为止已报道的深红光/近红外光发光二极管(LED)中的最高值。在这种高效的OLED器件中,采用TAPC作为空穴传输层,PO-T2T作为电子传输层,实现选择性地空穴注入HOMO,电子注入SOMO,形成近100%内量子效率的荧光双线激发态。
Features and Benefits
- High Purity: Assay of ≥99% (HPLC) ensures reliable performance and consistency in applications.
- Molecular Weight: 909.8 g/mol, facilitating accurate formulation and dosing in various applications.
- Optical Properties: Exhibits a maximum absorbance at λmax of 272 nm in dichloromethane, enhancing its utility in photonic applications.
- Stable Performance: The compound is solid at room temperature, making it easy to handle and process.
- Electron Transport Capabilities: Functions effectively as an electron transport layer (ETL) and hole-blocking material in OLEDs.
- Versatile Applications: Ideal for use in OLEDs, organic photovoltaics (OPVs), and other organic electronic devices, making it a valuable compound across multiple industries.
- Enhanced Device Efficiency: The ability to facilitate efficient charge transport improves the performance of OLEDs, contributing to higher brightness and lower power consumption.
- Innovative Device Architecture: PO-T2T enables the development of tandem OLEDs with excellent efficiencies, demonstrating its potential in advanced organic electronic applications.
- Research and Development Utility: An excellent candidate for researchers exploring new materials in organic electronics, providing a reliable platform for experimentation and innovation.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
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The photophysics of an exciplex state formed between a small molecule and a polymer is investigated in this work. The results obtained with this blend show the strong potential of polymer-small-molecule blends for triplet harvesting in organic light-emitting diodes (OLEDs)
Yi-Tzu Hung et al.
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Two new nonconjugated linked dicarbazole materials, dCzPSi and dCzPSO2, with high triplet energy were synthesized and characterized. dCzPSi and dCzPSO2 were adopted as unipolar host materials for the green thermally activated delayed fluorescence (TADF) emitter (4CzIPN) to achieve high-efficiency organic
Tzu-Chieh Lin et al.
Nature communications, 9(1), 3111-3111 (2018-08-08)
The lack of structural information impeded the access of efficient luminescence for the exciplex type thermally activated delayed fluorescence (TADF). We report here the pump-probe Step-Scan Fourier transform infrared spectra of exciplex composed of a carbazole-based electron donor (CN-Cz2) and