908886
N-Cyano-4-methoxy-picolinimidamide
≥95%, powder or crystals
Synonym(s):
Weix ligand
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About This Item
Empirical Formula (Hill Notation):
C8H8N4O
CAS Number:
Molecular Weight:
176.18
MDL number:
UNSPSC Code:
12352111
NACRES:
NA.22
Product Name
N-Cyano-4-methoxy-picolinimidamide, ≥95%
SMILES string
N(C(=N)c1nccc(c1)OC)C#N
InChI
1S/C8H8N4O/c1-13-6-2-3-11-7(4-6)8(10)12-5-9/h2-4H,1H3,(H2,10,12)
InChI key
LEWHOCRDELQPCV-UHFFFAOYSA-N
assay
≥95%
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
220-225 °C
Related Categories
Application
This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Eric C Hansen et al.
Nature chemistry, 8(12), 1126-1130 (2016-11-23)
Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well
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