912778
sBOX(iPr)
≥95%, powder, solid or chunks
Synonym(s):
Diisopropyl 2,2′-(cyclopropane-1,1-diyl)(4S,4′S)-bis(4,5-dihydrooxazole-4-carboxylate)
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About This Item
Empirical Formula (Hill Notation):
C17H24N2O6
CAS Number:
Molecular Weight:
352.38
MDL number:
UNSPSC Code:
12352005
NACRES:
NA.22
Product Name
sBOX(iPr), ≥95%
InChI key
JNHLVSXLRZSBTG-RYUDHWBXSA-N
SMILES string
N1=C(OC[C@H]1C(=O)OC(C)C)C3(CC3)C2=N[C@@H](CO2)C(=O)OC(C)C
assay
≥95%
form
(Powder or Solid or Chunks)
storage temp.
2-8°C
Related Categories
Application
sBOX(iPr) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Niankai Fu et al.
Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new
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