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913200

(R)-BIDIME

Name: (<I>R</I>)-BIDIME
Brand: ALDRICH

≥97%, powder

Synonym(s):

(R)-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole

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About This Item

Empirical Formula (Hill Notation):

C₁₉H₂₃O₃P

CAS Number:

1338454-03-7

Molecular Weight:

330.36

MDL number:

MFCD30748198

UNSPSC Code:

12352200

NACRES:

NA.22

Assay:

≥97%

Form:

powder

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Properties

Product Name

(R)-BIDIME, ≥97%

Quality Segment

100

product line

Buchwald Ligand

assay

≥97%

form

powder

optical purity

ee: ≥99% (HPLC)

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand

functional group

phosphine

SMILES string

P1(COc2c1c(ccc2)c3c(cccc3OC)OC)C(C)(C)C

InChI key

BWPDUHMFZCEKIP-UHFFFAOYSA-N

Description

Application

(R)-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.

Other Notes

Synthesis of Chiral α-Amino Tertiary Boronic Esters by Enantioselective Hydroboration of α-Arylenamides

Legal Information

Sold in collaboration with Zejun Pharmaceuticals

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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