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Merck
CN

916129

Sigma-Aldrich

1,10-Phenanthroline nickel (ll) dichloride

powder or crystals

Synonym(s):

phenNiCl2

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About This Item

Empirical Formula (Hill Notation):
C12H8Cl2N2Ni
CAS Number:
22980-76-3
Molecular Weight:
309.80
MDL number:
MFCD32706956
UNSPSC Code:
12352200
NACRES:
NA.22

Key Documents

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Product Name

1,10-Phenanthroline nickel (ll) dichloride,

form

powder or crystals

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Ni].Cl.Cl.n1c2c3ncccc3ccc2ccc1

InChI

1S/C12H8N2.2ClH.Ni/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;

InChI key

CHVPLVVTLIMTJX-UHFFFAOYSA-N

Related Categories

Application

1,10-Phenanthroline nickel (ll) dichloride is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

Other Notes

Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR5210

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Zheng-Jun Wang et al.
Organic letters, 21(16), 6543-6547 (2019-08-08)
A radical-mediated functionalization of allyl alcohol derived partners with a variety of alkyl 1,4-dihydropyridines via photoredox/nickel dual catalysis is described. This transformation transpires with high linear and E-selectivity, avoiding the requirement of harsh conditions (e.g., strong base, elevated temperature). Additionally

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