916129
1,10-Phenanthroline nickel (ll) dichloride
powder or crystals
Synonym(s):
phenNiCl2
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About This Item
Empirical Formula (Hill Notation):
C12H8Cl2N2Ni
CAS Number:
Molecular Weight:
309.80
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22
Form:
powder or crystals
Product Name
1,10-Phenanthroline nickel (ll) dichloride,
SMILES string
[Ni].Cl.Cl.n1c2c3ncccc3ccc2ccc1
InChI key
CHVPLVVTLIMTJX-UHFFFAOYSA-N
InChI
1S/C12H8N2.2ClH.Ni/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Quality Level
Application
1,10-Phenanthroline nickel (ll) dichloride is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Zheng-Jun Wang et al.
Organic letters, 21(16), 6543-6547 (2019-08-08)
A radical-mediated functionalization of allyl alcohol derived partners with a variety of alkyl 1,4-dihydropyridines via photoredox/nickel dual catalysis is described. This transformation transpires with high linear and E-selectivity, avoiding the requirement of harsh conditions (e.g., strong base, elevated temperature). Additionally
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