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917745

[Ni(dtbbpy)(H2O)4]Cl2

powder

别名:

Nickel(2+), tetraaqua[4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-κN1,κN1′]-, chloride

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关于此项目

经验公式（希尔记法）:
C18H32Cl2N2NiO4
化学文摘社编号:
2035424-75-8
分子量:
470.06
MDL number:
MFCD33021751
UNSPSC Code:
12161600
NACRES:
NA.22
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产品名称

[Ni(dtbbpy)(H2O)4]Cl2,

form

powder

Quality Segment

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Ni+2]1([NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(C)(C)C)C(C)(C)C)(O)(O)(O)O.C

InChI key

UTKNAEDPSHMNCR-UHFFFAOYSA-J

Application

[Ni(dtbbpy)(H2O)4]Cl2 is a Ni precatalyst used in a series of Ni/photoredox dual catalysis cross-coupling reactions. These transformations include the decarboxylative coupling of oxetanyl amino acids with aryl halides.

Other Notes

Dual Photoredox/Nickel-Catalyzed Conversion of Aryl Halides to Aryl Aminooxetanes: Computational Evidence for a Substrate-Dependent Switch in Mechanism

1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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