918997
AndrewPhos
≥95%, powder
Synonym(s):
14,14-Dimethyl-13-(3-methoxy-2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)-1,4-dioxa-13-phosphadispiro[4.1.5.3]pentadecane
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About This Item
Empirical Formula (Hill Notation):
C36H53O3P
CAS Number:
Molecular Weight:
564.78
MDL number:
UNSPSC Code:
12352112
NACRES:
NA.22
Product Name
AndrewPhos, ≥95%
InChI key
CNDZLFAQJZQSQK-UHFFFAOYSA-N
SMILES string
P3(C4(CC5(OCCO5)CC3(C)C)CCCCC4)c1c(cccc1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC
assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand
functional group
phosphine
storage temp.
−20°C
Quality Level
Related Categories
Application
AndrewPhos is a biaryl phosphorinane ligand for Pd catalysis. This ligand has been used in a variety of Pd-catalyzed reactions including the sulfonamidation of aryl halides, C-O couplings, and C-N couplings.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands.
Laffoon S D, et al.
ACS Catalysis, 9(12), 11691-11708 (2019)
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