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918997

AndrewPhos

Name: AndrewPhos
Brand: ALDRICH

≥95%, powder

Synonym(s):

14,14-Dimethyl-13-(3-methoxy-2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)-1,4-dioxa-13-phosphadispiro[4.1.5.3]pentadecane

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About This Item

Empirical Formula (Hill Notation):

C₃₆H₅₃O₃P

CAS Number:

2380310-03-0

Molecular Weight:

564.78

MDL number:

MFCD34549923

UNSPSC Code:

12352112

NACRES:

NA.22

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Properties

Product Name

AndrewPhos, ≥95%

Quality Segment

100

product line

Buchwald Ligand

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand

functional group

phosphine

storage temp.

−20°C

SMILES string

P3(C4(CC5(OCCO5)CC3(C)C)CCCCC4)c1c(cccc1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC

InChI key

CNDZLFAQJZQSQK-UHFFFAOYSA-N

Description

Application

AndrewPhos is a biaryl phosphorinane ligand for Pd catalysis. This ligand has been used in a variety of Pd-catalyzed reactions including the sulfonamidation of aryl halides, C-O couplings, and C-N couplings.

Other Notes

Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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