919578
PAd2-DalPhos Ni(o-tolyl)Cl
powder
Synonym(s):
(PAd2-Dalphos)Ni()
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About This Item
Empirical Formula (Hill Notation):
C33H43ClNiO6P2
Molecular Weight:
691.78
UNSPSC Code:
12161600
NACRES:
NA.22
Product Name
PAd2-DalPhos Ni(o-tolyl)Cl,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Related Categories
Application
PAd2-DalPhos Ni(o-tolyl)Cl is an air-stable precatalyst developed in the Stradiotto lab for cross coupling of primary heteroarylamines and (hetero)aryl chlorides.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Jillian S K Clark et al.
Angewandte Chemie (International ed. in English), 58(19), 6391-6395 (2019-03-16)
Base-metal catalysts capable of enabling the assembly of heteroatom-dense molecules by cross-coupling of primary heteroarylamines and (hetero)aryl chlorides, while sought-after given the ubiquity of unsymmetrical di(hetero)arylamino fragments in pharmacophores, are unknown. Herein, we disclose the new "double cage" bisphosphine PAd2-DalPhos
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