921750
endo-N-Methyl-5-norbornene-2-carboxamide
≥95%, powder
Synonym(s):
endo-N-Methylbicyclo[2.2.1]hept-5-ene-2-carboxamide
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About This Item
Empirical Formula (Hill Notation):
C9H13NO
CAS Number:
Molecular Weight:
151.21
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Product Name
endo-N-Methyl-5-norbornene-2-carboxamide, ≥95%
assay
≥95%
form
powder
mp
105-108 °C
storage temp.
2-8°C
Quality Level
Related Categories
Application
endo-N-Methyl-5-norbornene-2-carboxamide is a norbornene ligand developed in the lab of Guanbing Dong for use in norbornene/palladium catalysis.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Zhe Dong et al.
Angewandte Chemie (International ed. in English), 54(43), 12664-12668 (2015-09-04)
Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.
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