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921750

endo-N-Methyl-5-norbornene-2-carboxamide

≥95%, powder

Synonym(s):

endo-N-Methylbicyclo[2.2.1]hept-5-ene-2-carboxamide

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About This Item

Empirical Formula (Hill Notation):
C9H13NO
CAS Number:
13295-40-4
Molecular Weight:
151.21
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
MFCD00970638
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Product Name

endo-N-Methyl-5-norbornene-2-carboxamide, ≥95%

Quality Level

100

assay

≥95%

form

powder

mp

105-108 °C

storage temp.

2-8°C

Application

endo-N-Methyl-5-norbornene-2-carboxamide is a norbornene ligand developed in the lab of Guanbing Dong for use in norbornene/palladium catalysis.

Other Notes

Ortho C-H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Zhe Dong et al.
Angewandte Chemie (International ed. in English), 54(43), 12664-12668 (2015-09-04)
Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.

Global Trade Item Number

SKUGTIN
921750-100MG04065266574395