922919
Pd(IPr)(acac)Cl
powder
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About This Item
Empirical Formula (Hill Notation):
C32H43ClN2O2Pd
CAS Number:
Molecular Weight:
629.57
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
Product Name
Pd(IPr)(acac)Cl,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
Pd(IPr)(acac)Cl is a Pd-catalyst that can be used in a broad range of reactions, including cross-coupling, C-H functionalization, electrophilic additions.
Other Notes
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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[Pd(NHC)(acac)Cl]: Well-Defined, Air-Stable, and Readily Available Precatalysts for Suzuki and Buchwald−Hartwig Cross-coupling (Transamidation) of Amides and Esters by N−C/O−C Activation.
Zhou T, et al.
Organic Letters, 21, 3304-3309 (2019)
Nicolas Marion et al.
The Journal of organic chemistry, 71(10), 3816-3821 (2006-05-06)
A very straightforward synthesis of (IPr)Pd(acac)Cl from two commercially available starting materials, Pd(acac)2 and IPr.HCl [acac = acetylacetonate; IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene], has been developed. The resulting complex, (IPr)Pd(acac)Cl (1), has proven to be a highly active PdII precatalyst in the
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