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923451

(PhMPhos)PdCl₂

Name: (PhMPhos)PdCl<SUB>2</SUB>
Brand: ALDRICH

powder, complex with CH₂Cl₂

Synonym(s):

1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride

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About This Item

Empirical Formula (Hill Notation):

C₄₂H₄₈Cl₂FeP₂Pd

CAS Number:

2768152-19-6

Molecular Weight:

847.95

UNSPSC Code:

12352101

NACRES:

NA.21

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Properties

Product Name

(PhMPhos)PdCl₂, complex with CH₂Cl₂

Quality Level

100

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

ClCCl.[Cl-][Pd+2]1([Cl-])[P](C=2C=CC=CC2)(C=3C=CC=CC3)[C-]45[CH]6=[CH]7[CH]8=[CH]4[Fe+2]789%10%11%1265[CH]=%13[CH]%12=[CH]%11[C-]%10([CH]%139)[P]1(C%14%15CC%16CC(CC(C%16)C%14)C%15)C%17%18CC%19CC(CC(C%19)C%17)C%18

InChI

InChI=1S/C25H34P.C17H14P.CH2Cl2.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h1-4,17-22H,5-16H2;1-14H;1H2;2*1H;;/q2*-1;;;;2*+2/p-2

InChI key

CPZZSCIFYJFGRL-UHFFFAOYSA-L

Description

Application

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

wgk

WGK 3

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number

MKCZ3995

MKCZ8766

MKCV3420

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Global Trade Item Number

SKU	GTIN
923451-500MG	04065267050393
923451-100MG	04065267050386