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Merck
CN

926736

Sigma-Aldrich

MNBO

≥95%, powder

Synonym(s):

N-Benzyl-N-(2-methylnaphthalen-1-yl)oxalamide

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About This Item

Empirical Formula (Hill Notation):
C20H18N2O2
CAS Number:
Molecular Weight:
318.37
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.21
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Product Name

MNBO, ≥95%

Quality Level

Assay

≥95%

form

powder

mp

202-203 °C

storage temp.

−20°C

SMILES string

N(Cc3ccccc3)C(=O)C(=O)Nc1c2c(ccc1C)cccc2

InChI key

QOOOSPCWFVCKFK-UHFFFAOYSA-N

Application

MNBO is a ligand for the copper-catalyzed Ullman-Ma cross-coupling reaction.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Jie Gao et al.
Organic letters, 19(11), 2809-2812 (2017-05-23)
A class of N-(naphthalen-1-yl)-N'-alkyl oxalamides have been proven to be powerful ligands, making a coupling reaction of (hetero)aryl iodides with primary amines proceed at 50 °C with only 0.01 mol % of Cu2O and ligand as well as a coupling

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