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926736

MNBO

Name: MNBO
Brand: ALDRICH

≥95%, powder

Synonym(s):

N-Benzyl-N-(2-methylnaphthalen-1-yl)oxalamide

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About This Item

Empirical Formula (Hill Notation):

C₂₀H₁₈N₂O₂

CAS Number:

2072108-68-8

Molecular Weight:

318.37

MDL number:

MFCD34181626

UNSPSC Code:

12352101

NACRES:

NA.21

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Properties

Product Name

MNBO, ≥95%

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reagent type: ligand
reaction type: Ullmann Reaction

mp

202-203 °C

storage temp.

−20°C

SMILES string

N(Cc3ccccc3)C(=O)C(=O)Nc1c2c(ccc1C)cccc2

InChI key

QOOOSPCWFVCKFK-UHFFFAOYSA-N

Description

Application

MNBO is a ligand for the copper-catalyzed Ullman-Ma cross-coupling reaction.

Other Notes

Discovery of N-(Naphthalen-1-yl)-N′-alkyl Oxalamide Ligands Enables Cu-Catalyzed Aryl Amination with High Turnovers

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Discovery of N-(Naphthalen-1-yl)-N'-alkyl Oxalamide Ligands Enables Cu-Catalyzed Aryl Amination with High Turnovers.

Jie Gao et al.

Organic letters, 19(11), 2809-2812 (2017-05-23)

A class of N-(naphthalen-1-yl)-N'-alkyl oxalamides have been proven to be powerful ligands, making a coupling reaction of (hetero)aryl iodides with primary amines proceed at 50 °C with only 0.01 mol % of Cu2O and ligand as well as a coupling

Global Trade Item Number

SKU	GTIN
926736-1G	04065267990033
926736-250MG	04065267990040