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927155

DPEO

Name: DPEO
Brand: ALDRICH

≥95%, powder

Synonym(s):

N,N′-Bis(2-phenylethyl)ethanediamide

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About This Item

Empirical Formula (Hill Notation):

C₁₈H₂₀N₂O₂

CAS Number:

14040-79-0

Molecular Weight:

296.36

UNSPSC Code:

12352101

NACRES:

NA.21

MDL number:

MFCD00030029

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Properties

Product Name

DPEO, ≥95%

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reagent type: ligand
reaction type: Ullmann Reaction

SMILES string

O=C(C(NCCC1=CC=CC=C1)=O)NCCC2=CC=CC=C2

InChI

1S/C18H20N2O2/c21-17(19-13-11-15-7-3-1-4-8-15)18(22)20-14-12-16-9-5-2-6-10-16/h1-10H,11-14H2,(H,19,21)(H,20,22)

InChI key

QZXQKYMXZRGKLB-UHFFFAOYSA-N

Description

Application

DPEO is a ligand for the copper-catalyzed coupling of aryl halides and alkyl alcohols.

Other Notes

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H319,H400

pcodes

P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number

0000158530

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Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction.

Zhixiang Chen et al.

Journal of the American Chemical Society, 141(8), 3541-3549 (2019-01-29)

A robust and practical protocol for preparing alkyl aryl ethers has been developed, which relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero)aryl halides. The reaction scope is very general for a variety of coupling partners

Global Trade Item Number

SKU	GTIN
927155-250MG	04065267174792
927155-1G	04065267174785