928917
[CF3]8-DPPF
≥95%, powder
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About This Item
Empirical Formula (Hill Notation):
C42H20F24FeP2
CAS Number:
Molecular Weight:
1098.36
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.21
Product Name
[CF3]8-DPPF, ≥95%
SMILES string
C[Fe]C.FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)c3cccc3)=C1)(F)F.FC(C4=CC(C(F)(F)F)=CC(P(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)c6cccc6)=C4)(F)F
assay
≥95%
form
powder
reaction suitability
reagent type: ligand
mp
154-155 °C
functional group
phosphine
Quality Level
Related Categories
Application
[CF3]8-DPPF is a ferrocenyl phosphine ligand used in a mild Ni catalyzed C-N cross coupling reaction.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Richard Y Liu et al.
Journal of the American Chemical Society, 142(9), 4500-4507 (2020-02-11)
Palladium-catalyzed amination reactions using soluble organic bases have provided a solution to the many issues associated with heterogeneous reaction conditions. Still, homogeneous C-N cross-coupling approaches cannot yet employ bases as weak and economical as trialkylamines. Furthermore, organic base-mediated methods have
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