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Merck
CN

928917

[CF3]8-DPPF

≥95%, powder

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关于此项目

经验公式（希尔记法）:
C42H20F24FeP2
化学文摘社编号:
70236-68-9
分子量:
1098.36
MDL number:
MFCD34622485
UNSPSC Code:
41116107
NACRES:
NA.21

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产品名称

[CF3]8-DPPF, ≥95%

SMILES string

C[Fe]C.FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)c3cccc3)=C1)(F)F.FC(C4=CC(C(F)(F)F)=CC(P(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)c6cccc6)=C4)(F)F

assay

≥95%

form

powder

reaction suitability

reagent type: ligand

mp

154-155 °C

functional group

phosphine

Quality Level

100

相关类别

Application

[CF3]8-DPPF is a ferrocenyl phosphine ligand used in a mild Ni catalyzed C-N cross coupling reaction.

Other Notes

The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Richard Y Liu et al.
Journal of the American Chemical Society, 142(9), 4500-4507 (2020-02-11)
Palladium-catalyzed amination reactions using soluble organic bases have provided a solution to the many issues associated with heterogeneous reaction conditions. Still, homogeneous C-N cross-coupling approaches cannot yet employ bases as weak and economical as trialkylamines. Furthermore, organic base-mediated methods have

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