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Merck
CN

929743

[Ir(df(CF3)ppy)2(4,4′-(OMe)2bpy]BF4

≥95%, powder or chunks

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About This Item

Empirical Formula (Hill Notation):
C36H22BF14IrN4O2
CAS Number:
2598267-80-0
Molecular Weight:
1011.59
MDL number:
MFCD34704609
UNSPSC Code:
12352101
NACRES:
NA.21

Key Documents

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Product Name

[Ir(df(CF3)ppy)2(4,4′-(OMe)2bpy]BF4, ≥95%

SMILES string

FC1=C(C2=CC(F)=C1)C3=[N](C=C(C=C3)C(F)(F)F)[Ir]452([N]6=CC=C(C=C6C7=CC(OC)=CC=[N]75)OC)[N]8=CC(C(F)(F)F)=CC=C8C9=C(C=C(C=C94)F)F.FB(F)(F)F

assay

≥95%

form

powder or chunks

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

Quality Level

100

Related Categories

Application

[Ir(df(CF3)ppy)2(4,4′-(OMe)2bpy]BF4 is a versatile photocatalyst that can be used for a variety of synthetic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Visible-Light-Induced Synthesis of 1,2,3,4-Tetrahydroquinolines through Formal [4+2] Cycloaddition of Acyclic α,β-Unsaturated Amides and Imides with N,N-Dialkylanilines

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Kennosuke Itoh et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(16), 5171-5179 (2020-12-11)
1,2,3,4-Tetrahydroquinolines should be applicable to the development of new pharmaceutical agents. A facile synthesis of 1,2,3,4-tetrahydroquinolines that is achieved by a photoinduced formal [4+2] cycloaddition reaction of acyclic α,β-unsaturated amides and imides with N,N-dialkylanilines under visible-light irradiation, in which a

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