930121
RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN]
powder or crystals
别名:
[N-[(1S,2S)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌
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关于此项目
经验公式（希尔记法）:
C31H35ClN2O2RuS
化学文摘社编号:
分子量:
636.21
NACRES:
NA.21
UNSPSC Code:
12352116
MDL number:
产品名称
RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN],
form
powder or crystals
Quality Segment
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
>175 °C
greener alternative category
storage temp.
2-8°C
SMILES string
CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
InChI key
AZFNGPAYDKGCRB-XCPIVNJJSA-M
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
催化剂涉及：
手性氨基酰胺烷基配合物热分解研究中的反应物
- 亚胺和酮的不对称转移加氢
- 分子内不对称还原胺化
- 末端烯烃的串联氢甲酰化/氢化
手性氨基酰胺烷基配合物热分解研究中的反应物
RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium used for asymmetric hydrogenation reactions.
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable