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930202

3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride

Name: 3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride
Brand: ALDRICH

≥95%, powder

Synonym(s):

3-(2,6-diisopropylphenyl)-4,5-dimethyl-1-(2,4,6-trimethylbenzyl)-1H-imidazol-3-ium chloride

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About This Item

Empirical Formula (Hill Notation):

C₂₇H₃₇ClN₂

CAS Number:

1807855-96-4

Molecular Weight:

425.05

UNSPSC Code:

12352005

NACRES:

NA.21

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Properties

Product Name

3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride, ≥95%

Quality Segment

100

assay

≥95%

form

powder

reaction suitability

reagent type: ligand
reaction type: Cross Couplings

SMILES string

[Cl-].C=1C=C(C(=C(C1)C(C)C)[N+]2=CN(C(=C2C)C)CC=3C(=CC(=CC3C)C)C)C(C)C

InChI

1S/C27H37N2.ClH/c1-17(2)24-11-10-12-25(18(3)4)27(24)29-16-28(22(8)23(29)9)15-26-20(6)13-19(5)14-21(26)7;/h10-14,16-18H,15H2,1-9H3;1H/q+1;/p-1

InChI key

VEFYQHOVUBFLHY-UHFFFAOYSA-M

Description

Application

3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride is a highly hindered and flexible unsymmetrical NHC ligand for hydrofunctionalization reactions. When combined with a group 11 metal (Cu, Au, Ag), this ligand can be used in hydroelement additions, element-element additions, carbo-element additions, hydrations, hydroaminations, hydroarylations, hyroalkoxylations, hydrocarboxylations, cyclizations, hydrofluorinations, as well as a variety of combined processes using tandem reactions.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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