931861
(3aR,3′aR,8aS,8′a′S)-2,2′-Cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole]
≥95%, powder
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About This Item
Empirical Formula (Hill Notation):
C23H20N2O2
CAS Number:
Molecular Weight:
356.42
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Product Name
(3aR,3′aR,8aS,8′a′S)-2,2′-Cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole], ≥95%
SMILES string
N1=C(O[C@@H]6[C@H]1c7c(cccc7)C6)C5(CC5)C2=N[C@H]3[C@@H](O2)Cc4c3cccc4
InChI
1S/C23H20N2O2/c1-3-7-15-13(5-1)11-17-19(15)24-21(26-17)23(9-10-23)22-25-20-16-8-4-2-6-14(16)12-18(20)27-22/h1-8,17-20H,9-12H2/t17-,18-,19+,20+/m0/s1
InChI key
QFXUVUBVPPOPQZ-VNTMZGSJSA-N
assay
≥95%
form
powder
Quality Level
Application
(3aR,3′aR,8aS,8′a′S)-2,2′-Cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole] is a bisoxazoline (BOX) ligand for asymmetric catalysis.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Copper(I)-catalyzed highly enantioselective [3+3]-cycloaddition of ?-alkyl enoldiazoacetates with nitrones
Dong K, et al.
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 7, 1653-1657 (2020)
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