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937355

ImPy-Trip-IPr*

Name: ImPy-Trip-IPr*
Brand: ALDRICH

≥95%, powder or crystals

别名:

2‐[2,6‐Bis(diphenylmethyl)‐4‐methylphenyl]‐5‐[2,4,6‐tris(propan‐2‐yl)phenyl]‐2H‐4Λ5‐imidazo[1,5‐a]pyridin‐4‐ylium chloride

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关于此项目

经验公式（希尔记法）:

C₅₅H₅₅ClN₂

化学文摘社编号:

2983007-59-4

分子量:

779.49

NACRES:

NA.21

Assay:

≥95%

Form:

powder or crystals

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属性

产品名称

ImPy-Trip-IPr*, ≥95%

Quality Segment

100

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
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sustainability

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color

white to off-white

functional group

(Carbene)

greener alternative category

Aligned

SMILES string

CC(C=C1C(C2=CC=CC=C2)C3=CC=CC=C3)=CC(C(C4=CC=CC=C4)C5=CC=CC=C5)=C1N6C=[N+]7C(C=CC=C7C8=C(C(C)C)C=C(C(C)C)C=C8C(C)C)=C6.[Cl-]

InChI

1S/C55H55N2.ClH/c1-37(2)45-33-47(38(3)4)54(48(34-45)39(5)6)51-30-20-29-46-35-56(36-57(46)51)55-49(52(41-21-12-8-13-22-41)42-23-14-9-15-24-42)31-40(7)32-50(55)53(43-25-16-10-17-26-43)44-27-18-11-19-28-44;/h8-39,52-53H,1-7H3;1H/q+1;/p-1

InChI key

RFDIMPRGVRMUES-UHFFFAOYSA-M

说明

General description

ImPy-Trip-IPr* is a member of a class of biaryl NHC ligands utilizing sterics to facilitate a well-defined L-shaped NHC. The unique shape allows for the development of cross-coupling reactions not possible with other NHC ligands, as well as an improvement in catalytic efficiency with many existing methods. Readily forms complexes with Pd, as well as Au, Cu, Rh, and other metals.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Active in the following reactions:

Suzuki-Miyarua cross-coupling
Buchwald-Hartwig amination
Hydroxylation of aryl chlorides

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c