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Merck
CN

937355

Sigma-Aldrich

ImPy-Trip-IPr*

greener alternative

≥95%, powder or crystals

别名:

2‐[2,6‐Bis(diphenylmethyl)‐4‐methylphenyl]‐5‐[2,4,6‐tris(propan‐2‐yl)phenyl]‐2H‐4Λ5‐imidazo[1,5‐a]pyridin‐4‐ylium chloride

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关于此项目

经验公式（希尔记法）:
C55H55ClN2
CAS Number:
2983007-59-4
分子量:
779.49
NACRES:
NA.21

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Product Name

ImPy-Trip-IPr*, ≥95%

质量水平

100

方案

≥95%

表单

powder or crystals

反应适用性

reaction type: Cross Couplings

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

颜色

white to off-white

官能团

(Carbene)

环保替代产品分类

Aligned

SMILES字符串

CC(C=C1C(C2=CC=CC=C2)C3=CC=CC=C3)=CC(C(C4=CC=CC=C4)C5=CC=CC=C5)=C1N6C=[N+]7C(C=CC=C7C8=C(C(C)C)C=C(C(C)C)C=C8C(C)C)=C6.[Cl-]

InChI

1S/C55H55N2.ClH/c1-37(2)45-33-47(38(3)4)54(48(34-45)39(5)6)51-30-20-29-46-35-56(36-57(46)51)55-49(52(41-21-12-8-13-22-41)42-23-14-9-15-24-42)31-40(7)32-50(55)53(43-25-16-10-17-26-43)44-27-18-11-19-28-44;/h8-39,52-53H,1-7H3;1H/q+1;/p-1

InChI key

RFDIMPRGVRMUES-UHFFFAOYSA-M

相关类别

一般描述

ImPy-Trip-IPr* is a member of a class of biaryl NHC ligands utilizing sterics to facilitate a well-defined L-shaped NHC. The unique shape allows for the development of cross-coupling reactions not possible with other NHC ligands, as well as an improvement in catalytic efficiency with many existing methods. Readily forms complexes with Pd, as well as Au, Cu, Rh, and other metals.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Active in the following reactions:
  • Suzuki-Miyarua cross-coupling
  • Buchwald-Hartwig amination
  • Hydroxylation of aryl chlorides

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW4495

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