94327
Deoxo-Fluor solution
50% in THF
Synonym(s):
Bis(2-methoxyethyl)aminosulfur trifluoride solution
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About This Item
Empirical Formula (Hill Notation):
C6H14F3NO2S
CAS Number:
Molecular Weight:
221.24
UNSPSC Code:
12352101
PubChem Substance ID:
MDL number:
form
liquid
Quality Level
concentration
50% in THF
density
1.03-1.05 g/mL at 20 °C
storage temp.
2-8°C
SMILES string
COCCN(CCOC)S(F)(F)F
InChI
1S/C6H14F3NO2S/c1-11-5-3-10(4-6-12-2)13(7,8)9/h3-6H2,1-2H3
InChI key
APOYTRAZFJURPB-UHFFFAOYSA-N
Application
Reactant for:
- Fluorination reactions
- Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination
- Preparation of imidazole derivatives as CXCR3 antagonists
- Ring expansion reactions
- Synthesis of acyl azides from carboxylic acids
- Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides
Other Notes
Fluorinating agent with high thermal stability
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react. 2
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
<50.0 °F - closed cup
flash_point_c
< 10 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Lal et al.
The Journal of organic chemistry, 65(16), 4830-4832 (2000-08-24)
A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the fluorinating agent, bis(2-methoxyethyl)aminosulfur trifluoride, in the presence of SbCl(3).
R.P. Singh, J.M. Shreeve
Journal of Fluorine Chemistry, 116, 23-23 (2002)
Fluorinating agent with high thermal stability.
S. Lal-Gauri et al.
The Journal of Organic Chemistry, 64, 7048-7048 (1999)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 94327-250ML-F | 04061838233851 |