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Merck
CN

94908

Vinylbenzyl chloride

purum, mixture of isomers, ≥95.0%, stabilized

Synonym(s):

(Chloromethyl)styrene

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About This Item

Linear Formula:
H2C=CHC6H4CH2Cl
CAS Number:
Molecular Weight:
152.62
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
250-005-9
Beilstein/REAXYS Number:
2204384
MDL number:
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Product Name

Vinylbenzyl chloride, purum, mixture of isomers, ≥95.0%, stabilized

InChI key

QSDACPJNNYTTDP-UHFFFAOYSA-N

InChI

1S/2C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8;1-2-8-4-3-5-9(6-8)7-10/h2*2-6H,1,7H2

SMILES string

ClCc1ccc(C=C)cc1.ClCc2cccc(C=C)c2

vapor density

5.3 (vs air)

vapor pressure

1 mmHg ( 56.1 °C)

grade

purum

assay

≥95.0%

form

liquid

autoignition temp.

1139 °F

refractive index

n20/D 1.572 (lit.)
n20/D 1.572

bp

229 °C (lit.)

density

1.074 g/mL at 25 °C (lit.)

shipped in

wet ice

storage temp.

−20°C

Quality Level

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Application


  • RAFT homopolymerization of vinylbenzyl chloride with benzyl ethyl trithiocarbonate and synthesis of block copolymers from poly (VBC) macro-RAFT agent: The study discusses living radical polymerizations applied to the polymerization of vinylbenzyl chloride (Sato et al., 2014).

  • Quaternized poly (styrene-co-vinylbenzyl chloride) anion exchange membranes for alkaline water electrolysers: This paper details the use of a styrene and vinylbenzyl chloride co-polymer as the polymer backbone for developing anion exchange membranes (Vengatesan et al., 2015).

  • Polybenzimidazole-crosslinked poly (vinylbenzyl chloride) with quaternary 1, 4-diazabicyclo (2.2. 2) octane groups as high-performance anion exchange membrane: The research highlights the crosslinking of polybenzimidazole with poly(vinylbenzyl chloride), enhancing the membrane′s flexibility and strength in various states (Lu et al., 2015).

  • Preparation and characterization of sulfur-vinylbenzyl chloride polymer under optimized reaction conditions using inverse vulcanization: This study focuses on the reaction of 4-vinylbenzyl chloride with sulfur under optimized conditions to produce a linear sulfur-based polymer (Abbasi et al., 2021).

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

213.8 °F - closed cup

flash_point_c

101 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Marco Guerritore et al.
Polymers, 12(6) (2020-06-25)
The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. The HCLN composition, morphology and porous structure were
Véronique Lenoble et al.
Journal of colloid and interface science, 448, 473-481 (2015-03-17)
Three novel Ni(II)-Ion-Imprinted Polymer (IIP) were synthesized by precipitation polymerization of ethylene glycol dimethacrylate (crosslinker) with a complex of nickel(II) and vinylbenzyl iminodiacetic acid (VbIDA). The three IIPs were prepared with various mixtures of porogen solvents: methanol, methanol/2-methoxyethanol and methanol/acetonitrile

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