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Merck
CN

96738

(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl

≥95.0% (H-NMR)

Synonym(s):

(+)-(5,5′-Dichloro-6,6′-dimethoxy-1,1′-biphenyl)-2,2′-diyl-bis(diphenylphosphine), (+)-2,2′-Bis(diphenylphosphino)-5,5′-dichloro-6,6′-dimethoxy-1,1′-biphenyl, (R)-(+)-Cl-MeO-BIPHEP

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About This Item

Empirical Formula (Hill Notation):
C38H30Cl2O2P2
CAS Number:
185913-97-7
Molecular Weight:
651.50
UNSPSC Code:
12352101
PubChem Substance ID:
57653779
NACRES:
NA.22
MDL number:
MFCD03426987

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SMILES string

P(c3c(c(c(cc3)Cl)OC)c4c(ccc(c4OC)Cl)P(c6ccccc6)c5ccccc5)(c2ccccc2)c1ccccc1

InChI

1S/C38H30Cl2O2P2/c1-41-37-31(39)23-25-33(43(27-15-7-3-8-16-27)28-17-9-4-10-18-28)35(37)36-34(26-24-32(40)38(36)42-2)44(29-19-11-5-12-20-29)30-21-13-6-14-22-30/h3-26H,1-2H3

InChI key

GCBRCSSVOVNEIX-UHFFFAOYSA-N

assay

≥95.0% (H-NMR)

form

crystals

optical activity

[α]/D +59±4°, c = 1% in chloroform

functional group

chloro, phosphine

Quality Level

100

Related Categories

Other Notes

Transition metal complexes are used as catalysts for asymmetric hydrogenation; Eur Pat Appl 749973, 1995 (20.06.1995); Eur Pat Appl 1160237 (18.05.2001).

Legal Information

produced by Bayer

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ4813
BCCG7355
BCCF5904
BCCF2508
BCCD7062

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C. Laue et al.
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