A29585
Allyl bromide
ReagentPlus®, 99%, contains ≤1000 ppm propylene oxide as stabilizer
Synonym(s):
3-Bromo-1-propene
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About This Item
Linear Formula:
CH2=CHCH2Br
CAS Number:
Molecular Weight:
120.98
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-446-6
Beilstein/REAXYS Number:
605308
MDL number:
Assay:
99%
Form:
liquid
vapor density
4.2 (vs air)
Quality Level
product line
ReagentPlus®
assay
99%
form
liquid
autoignition temp.
554 °F
contains
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
refractive index
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
density
1.398 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
Application
Allyl bromide can be used as a reagent to prepare:
- Allyl ketones by Barbier-type allylation of various nitriles in the presence of Lewis acid.
- Homoallylic alcohols by reacting with aldehydes or ketones using zinc dust as a catalyst.
- 1,5-hexadiene by reductive C-C bond coupling using silver hydride cluster.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Facile and efficient synthesis of homoallylic alcohols using allyl bromide and commercial zinc dust
Ranu BC, et al.
Tetrahedron Letters, 36(27), 4885-4888 (1995)
Gas-phase synthesis of [Ag4H]+ and its mediation of the C-C coupling of allyl bromide
Khairallah GN and O'Hair, Richard AJ
Angewandte Chemie (International Edition in English), 44(5), 728-731 (2005)
Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction
Lee Adam S-Y and Lin L-S
Tetrahedron Letters, 41(45), 8803-8806 (2000)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| A29585-1KG | 04061833360095 |
| A29585-5G | 04061833360125 |
| A29585-500G | 04061833360118 |
| A29585-100G | 04061833360088 |
| A29585-3KG | 04061833360101 |