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A29585

烯丙基溴

Name: 烯丙基溴
Brand: ALDRICH

ReagentPlus^®, 99%, contains ≤1000 ppm propylene oxide as stabilizer

别名:

3-溴-1-丙烯

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关于此项目

线性分子式:

CH₂=CHCH₂Br

化学文摘社编号:

106-95-6

分子量:

120.98

UNSPSC Code:

12352101

NACRES:

NA.22

PubChem Substance ID:

24890713

EC Number:

203-446-6

Beilstein/REAXYS Number:

605308

MDL number:

MFCD00000244

Assay:

99%

Form:

liquid

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属性

vapor density

4.2 (vs air)

Quality Level

200

product line

ReagentPlus^®

assay

99%

form

liquid

autoignition temp.

554 °F

contains

≤1000 ppm propylene oxide as stabilizer

expl. lim.

7.3 %

refractive index

n20/D 1.469 (lit.)

bp

70-71 °C (lit.)

mp

−119 °C (lit.)

density

1.398 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

BrCC=C

InChI

1S/C3H5Br/c1-2-3-4/h2H,1,3H2

InChI key

BHELZAPQIKSEDF-UHFFFAOYSA-N

说明

Application

烯丙基溴可作为制备以下物质的反应剂：

在路易酸的作用下通过各种腈的 Barbier 型烯丙基化制备烯丙基酮。
使用锌粉作为催化剂，与醛类或酮类反应制备高烯丙醇。
通过氢化银团簇还原 C-C 键偶联制备 1,5-己二烯。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H225,H301 + H331,H314,H340,H350,H400

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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Facile and efficient synthesis of homoallylic alcohols using allyl bromide and commercial zinc dust

Ranu BC, et al.

Tetrahedron Letters, 36(27), 4885-4888 (1995)

Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction

Lee Adam S-Y and Lin L-S

Tetrahedron Letters, 41(45), 8803-8806 (2000)

Anionic Copolymerization of Styrene Sulfide with Elemental Sulfur (S8).

Jakub Wręczycki et al.

Materials (Basel, Switzerland), 13(11) (2020-06-11)

The superior ability of thiiranes (episulfides) to undergo ring-opening polymerization (ROP) in the presence of anionic initiators allows the preparation of chemically stable polysulfide homopolymers. Incorporation of elemental sulfur (S8) by copolymerization below the floor temperature of S8 permits the

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全球贸易项目编号

货号	GTIN
A29585-1KG	04061833360095
A29585-5G	04061833360125
A29585-100G	04061833360088
A29585-3KG	04061833360101
A29585-500G	04061833360118