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Merck
CN

A32608

Allyl glycidyl ether

≥99%

Synonym(s):

1-Allyloxy-2,3-epoxypropane, Allyl 2,3-epoxypropyl ether

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About This Item

Empirical Formula (Hill Notation):
C6H10O2
CAS Number:
106-92-3
Molecular Weight:
114.14
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24890754
EC Number:
203-442-4
Beilstein/REAXYS Number:
105871
MDL number:
MFCD00005143

Key Documents

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form

liquid

InChI key

LSWYGACWGAICNM-UHFFFAOYSA-N

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

SMILES string

C=CCOCC1OC1

vapor density

3.9 (vs air)

vapor pressure

4.7 mmHg ( 25 °C)

assay

≥99%

refractive index

n20/D 1.433 (lit.)

bp

154 °C (lit.)

density

0.962 g/mL at 25 °C (lit.)

Quality Level

200

Related Categories

General description

Allyl glycidyl ether (AGE) is a monomer that acts as a building block in the polymerization of poly(allyl glycidyl ether) by anionic ring opening mechanism. It is industrially prepared by the reacting allyl alcohol and epichlorohydrin.

Application

AGE can be used as a terminal epoxy group in the development of adhesive surfaces by hydrosilylation process. It can also be used in the synthesis of polymeric electrolytes for the fabrication of lithium batteries.
Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) catalyzed hydrosilylation of siloxanes to epoxysiloxanes.

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

134.6 °F - closed cup

flash_point_c

57 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SDBB4830
STBL3518
STBL4399
SDBB0561
STBL4243

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Y Koyama et al.
Bioconjugate chemistry, 7(3), 298-301 (1996-05-01)
Novel poly(ethylene glycol) (PEG) derivatives having pendant amino groups were prepared by copolymerization of allyl glycidyl ether with ethylene oxide followed by chemical modification of the double bond side chains. Dropwise addition of the mixture of monomers to the anionic
Minimally adhesive polymer surfaces prepared from star oligosiloxanes and star oligofluorosiloxanes
Grunlan MA, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(8), 2551-2566 (2006)
Challa Lahari et al.
Langmuir : the ACS journal of surfaces and colloids, 26(2), 1096-1106 (2009-12-10)
Effects of changes in hydrophobicity of polymeric support on structure and activity of alpha-chymotrypsin (E.C. 3.4.21.1) have been studied with copolymers of allyl glycidyl ether (AGE) and ethylene glycol dimethacrylate (EGDM) with increasing molar ratio of EGDM to AGE (cross-link
Bhalchandra K Vaidya et al.
Bioresource technology, 99(9), 3623-3629 (2007-09-04)
Macroporous polymer particles containing surface epoxy groups were synthesized for immobilization of Candida rugosa lipase (CRL). The effect of incorporation of two different sets of monomers [allyl glycidyl ether (AGE) and glycidyl methacrylate (GMA)] and the effect of crosslinking density
Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries
Barteau KP, et al.
Macromolecules, 46(22), 8988-8994 (2013)
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