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A35208

Allyl phenyl ether

Name: Allyl phenyl ether
Brand: ALDRICH

99%

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About This Item

Linear Formula:

C₆H₅OCH₂CH=CH₂

CAS Number:

1746-13-0

Molecular Weight:

134.18

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24890779

EC Number:

217-125-3

Beilstein/REAXYS Number:

1905622

MDL number:

MFCD00008644

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Properties

Quality Level

200

assay

99%

form

liquid

refractive index

n20/D 1.522 (lit.)

bp

192 °C (lit.)

density

0.978 g/mL at 25 °C (lit.)

SMILES string

C=CCOc1ccccc1

InChI

1S/C9H10O/c1-2-8-10-9-6-4-3-5-7-9/h2-7H,1,8H2

InChI key

POSICDHOUBKJKP-UHFFFAOYSA-N

Description

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Pd-catalyzed synthesis of allylic silanes from allylic ethers.

Ralph Moser et al.

Organic letters, 12(1), 28-31 (2009-12-03)

Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.

SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.

Anders Dahlén et al.

Organic letters, 5(22), 4085-4088 (2003-10-24)

[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrates.

Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.

M Mahmoudian et al.

Applied microbiology and biotechnology, 37(1), 28-31 (1992-04-01)

Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ether. These organisms included Aerococcus, Alcaligenes, Micrococcus and Staphylococcus spp. and

Global Trade Item Number

SKU	GTIN
A35208-25G	04061833467046