A8509
Lithium acetoacetate
≥90% (HPLC)
Synonym(s):
Acetoacetic acid lithium salt
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About This Item
Linear Formula:
CH3COCH2COOLi
CAS Number:
Molecular Weight:
108.02
Beilstein:
5774841
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
≥90% (HPLC)
form
powder
storage temp.
−20°C
SMILES string
[Li+].CC(=O)CC([O-])=O
InChI
1S/C4H6O3.Li/c1-3(5)2-4(6)7;/h2H2,1H3,(H,6,7);/q;+1/p-1
InChI key
UTLRZTUJSMCBHB-UHFFFAOYSA-M
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Application
Lithium acetoacetate can be used as an acetoacetate standard for the measurement of acetoacetate in biological samples. It can also be used for the preparation of sodium acetoacetate.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cristian Palmiere et al.
Legal medicine (Tokyo, Japan), 14(1), 17-20 (2011-12-20)
Isopropyl alcohol (IPA) is widely used as an industrial solvent and cleaning fluid. After ingestion or absorption, IPA is converted into acetone by alcohol dehydrogenase. However, in ketosis, acetone can be reduced to IPA. The aim of this study was
Preparation of crystalline lithium acetoacetate.
Hall LM
Analytical Biochemistry, 3(1), 75-80 (1962)
Hao Liang et al.
Journal of Cancer, 10(16), 3735-3745 (2019-07-25)
BDH2 is a short-chain dehydrogenase/reductase family member involved in several biological and pathological processes, including the utilization of cytosolic ketone bodies, immunocyte regulation and tumor progression. In this study, we first revealed that BDH2 was downregulated in HCC tissues by
Douglas Ganini et al.
Free radical biology & medicine, 51(3), 733-743 (2011-05-26)
Acetoacetate (AA) and 2-methylacetoacetate (MAA) are accumulated in metabolic disorders such as diabetes and isoleucinemia. Here we examine the mechanism of AA and MAA aerobic oxidation initiated by myoglobin (Mb)/H(2)O(2). We propose a chemiluminescent route involving a dioxetanone intermediate whose
Seppo Parkkila et al.
Chemical communications (Cambridge, England), 48(29), 3551-3553 (2012-03-03)
Acetoacetic acid and R-3-hydroxy-butyric acid (BHB) are "ketone bodies", metabolites produced during the ketogenic diet. We discovered that they inhibit in the submicromolar-micromolar range several carbonic anhydrase (CA, EC 4.2.1.1) isoforms involved in relevant physiologic processes such as lipogenesis and
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