ALD00386
Fe(dibm)3
solid
Synonym(s):
Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)
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About This Item
Empirical Formula (Hill Notation):
C27H45FeO6
CAS Number:
Molecular Weight:
521.49
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Product Name
Fe(dibm)3,
form
solid
Quality Segment
reaction suitability
reagent type: catalyst
core: iron, core: iron
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
mp
96-102 °C
greener alternative category
SMILES string
O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.[Fe+3]
InChI
1S/3C9H15O2.Fe/c3*1-6(2)8(10)5-9(11)7(3)4;/h3*5-7H,1-4H3;/q3*-1;+3
InChI key
LKNJSJQVZKKQHU-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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