ALD00580
5-Bromopyridin-3-yl sulfurofluoridate
≥95%
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About This Item
Empirical Formula (Hill Notation):
C5H3BrFNO3S
Molecular Weight:
256.05
NACRES:
NA.22
UNSPSC Code:
12352200
Assay:
≥95%
Form:
solid or liquid
Application
5-Bromopyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.
Related Content
The Sharpless Lab pursues useful new reactivity and general methods for selectively controlling chemical reactions.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| ALD00580-500MG | 04061833233641 |