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ALD00580

5-Bromopyridin-3-yl sulfurofluoridate

≥95%

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About This Item

Empirical Formula (Hill Notation):
C5H3BrFNO3S
Molecular Weight:
256.05
NACRES:
NA.22
UNSPSC Code:
12352200
Assay:
≥95%
Form:
solid or liquid
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Quality Segment

100

assay

≥95%

form

solid or liquid

storage temp.

2-8°C

Application

5-Bromopyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences.

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates
Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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