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About This Item
Empirical Formula (Hill Notation):
C10H13NOS
CAS Number:
Molecular Weight:
195.28
UNSPSC Code:
12352111
NACRES:
NA.22
MDL number:
SMILES string
S(CCNC(=O)C)c1ccccc1
InChI
1S/C10H13NOS/c1-9(12)11-7-8-13-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,11,12)
InChI key
RSOVUTMFSIKQHH-UHFFFAOYSA-N
form
solid
reaction suitability
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
84-85 °C
storage temp.
−20°C
Application
N-(2-(Phenylthio)ethyl)acetamide is a C-H activation ligand developed by the Yu Group for the Pd-catalyzed olefination/lactonization of C(sp3)-H bonds of free carboxylic acids.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Zhe Zhuang et al.
Journal of the American Chemical Society, 140(32), 10363-10367 (2018-07-22)
An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp3)-H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp3)-H bonds of free carboxylic acids without using an auxiliary. Subsequent lactonization of the
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