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Merck
CN

ALD00619

1,4-Diethyl 2-(1-pyridin-1-ium-yl)butanedioate ethylsulfate

≥95%

Synonym(s):

Fumarate-Pyr

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About This Item

Empirical Formula (Hill Notation):
C15H23NO8S
Molecular Weight:
377.41
NACRES:
NA.22
UNSPSC Code:
12352100
Assay:
≥95%
Form:
powder and chunks
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assay

≥95%

form

powder and chunks

mp

65-70 °C

Quality Level

Application

1,4-Diethyl 2-(1-pyridin-1-ium-yl)butanedioate ethylsulfate is a bench-stable pyridinium feedstock capable of acting as an inexpensive, scalable and practical building block toward the synthesis of a variety of C-4 alkyl pyridines.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Jin Choi et al.
Journal of the American Chemical Society, 143(31), 11927-11933 (2021-07-29)
The direct position-selective C-4 alkylation of pyridines has been a long-standing challenge in heterocyclic chemistry, particularly from pyridine itself. Historically this has been addressed using prefunctionalized materials to avoid overalkylation and mixtures of regioisomers. This study reports the invention of

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