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Merck
CN

B4007

1,2,4,5-Benzenetetracarboxylic acid

96%

Synonym(s):

Pyromellitic acid

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About This Item

Linear Formula:
C6H2(CO2H)4
CAS Number:
Molecular Weight:
254.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-879-5
MDL number:
Assay:
96%
Form:
powder
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assay

96%

form

powder

InChI key

CYIDZMCFTVVTJO-UHFFFAOYSA-N

InChI

1S/C10H6O8/c11-7(12)3-1-4(8(13)14)6(10(17)18)2-5(3)9(15)16/h1-2H,(H,11,12)(H,13,14)(H,15,16)(H,17,18)

SMILES string

OC(=O)c1cc(C(O)=O)c(cc1C(O)=O)C(O)=O

mp

281-284.5 °C (lit.)

Quality Level

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Application

1,2,4,5-Benzenetetracarboxylic acid is extensively used as a ligand in the synthesis of a wide range of metal-organic frameworks (MOFs) and coordination polymers. It can also be used to prepare supramolecular hydrogels by synthesizing gelators reacting 1,2,4,5-benzenetetracarboxylic acid with 4-hydroxy pyridine.

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

617.0 °F

flash_point_c

325 °C

ppe

dust mask type N95 (US), Eyeshields, Gloves


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New Two-Dimensional Metal? Organic Networks Constructed from 1, 2, 4, 5-Benzenetetracarboxylate and Chelate Ligands.
Li Y, et al.
Inorganic Chemistry, 42(9), 3119-3124 (2003)
New hydrogen-bonded supramolecular hydrogels and fibers derived from 1, 2, 4, 5-benzenetetracarboxylic acid and 4-hydroxypyridine.
Wang Y, et al.
Chemistry Letters (Jpn), 35(5), 548-549 (2006)
K-J Westin et al.
Journal of colloid and interface science, 282(2), 359-369 (2004-12-14)
The influence of four calcium complexing substances, i.e., citric acid (CIT), diethylenetriaminepentaacetic acid (DTPA), ethylenediaminetetraacetic acid (EDTA) and pyromellitic acid (PMA), on the crystal growth rate of the calcium carbonate polymorphs aragonite and calcite has been studied. Using a seeded
S Mallet et al.
Journal of chromatography. A, 853(1-2), 181-184 (1999-09-16)
Tartaric acid, used in pharmaceuticals and industrial food preparation, is an important by-product of wine preparation. It is produced by wine factories in large quantities and cannot be rejected into the environment. Wineries precipitate tartaric acid using calcium hydroxide and
X Xiong et al.
Electrophoresis, 19(12), 2243-2251 (1998-10-07)
The simultaneous separation and detection of small cations and anions by capillary zone electrophoresis (CZE) with indirect ultraviolet (UV) detection was successfully demonstrated in a background electrolyte (BGE) containing two UV-absorbing components. Benzylamine, imidazole, benzenesulfonic acid, sulfosalicylic acid, and pyromellitic

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