B4856
Diphenylmethanol
99%
Synonym(s):
Benzhydrol, Benzhydryl alcohol, Diphenyl carbinol
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About This Item
Linear Formula:
(C6H5)2CHOH
CAS Number:
Molecular Weight:
184.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-033-8
Beilstein/REAXYS Number:
1424379
MDL number:
Assay:
99%
Form:
powder
InChI key
QILSFLSDHQAZET-UHFFFAOYSA-N
InChI
1S/C13H12O/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13-14H
SMILES string
OC(c1ccccc1)c2ccccc2
assay
99%
form
powder
bp
297-298 °C (lit.)
Quality Level
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Application
Diphenylmethanol is used in the carbene-catalyzed dynamic kinetic resolution of α,α-disubstituted carboxylic esters. It can also be used in the chiral resolution of free-base and Ni(II) porphyrinoid complexes.
Storage Class
11 - Combustible Solids
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Carbene-Catalyzed Dynamic Kinetic Resolution of Carboxylic Esters.
Chen X, et al.
Journal of the American Chemical Society, 138(23), 7212-7215 (2016)
Alkylation of alcohols for gas chromatographic analysis by a phase transfer catalysis technique. Evaluation of benzhydrol benzylation in a one-phase system.
H Brink et al.
Acta pharmaceutica Suecica, 16(4), 247-262 (1979-01-01)
Kinetics of the hydrolysis of drugs containing the diphenyl-methyl-ether group.
O O Komolafe
Materia medica Polona. Polish journal of medicine and pharmacy, 17(2), 98-102 (1985-04-01)
Masanori Ichikawa et al.
Bioorganic & medicinal chemistry, 19(17), 5207-5224 (2011-08-02)
We have recently reported the discovery of the new benzhydrol template, which has a highly potent inhibitory activity for squalene synthase, as typified by compound 1 (SSI IC(50)=0.85 nM). However, it was composed of a pair of easy rotatable atropisomers.
L A Golovleva et al.
Biology bulletin of the Academy of Sciences of the USSR, 7(2), 143-151 (1980-03-01)
The possibility of complete degradation of DDT by Pseudomonas aeruginosa 640x was demonstrated in principle. A study of the conditions of degradation of DDT by this culture was made. It was demonstrated that only dechlorination of DDT to DDD is
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