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Merck
CN

B52808

1,2-Di(4-pyridyl)ethylene

97%

Synonym(s):

1,2-Bis(4-pyridyl)ethylene, 4,4′-Vinylenedipyridine

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About This Item

Empirical Formula (Hill Notation):
C12H10N2
CAS Number:
Molecular Weight:
182.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
236-432-3
Beilstein/REAXYS Number:
3865
MDL number:
Assay:
97%
Form:
crystals
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InChI key

MGFJDEHFNMWYBD-OWOJBTEDSA-N

InChI

1S/C12H10N2/c1(11-3-7-13-8-4-11)2-12-5-9-14-10-6-12/h1-10H/b2-1+

SMILES string

c1cc(ccn1)\C=C\c2ccncc2

assay

97%

form

crystals

Quality Level

Application

1,2-Di(4-pyridyl)ethylene is extensively used as a ligand/linker in the synthesis of a variety of metal-organic frameworks(MOFs) and coordination polymers (CPs). It is employed in the synthesis of:
  • Expanding and shrinking cadmium-based pillared layer coordination polymers showing selective guest adsorption.
  • Dinuclear zinc complex that exhibits photocontrolled fluorescence.
  • Platinum-based 3-D tetragonal prisms via multicomponent coordination-driven self-assembly.

pictograms

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Topochemical Photodimerization in the Coordination Polymer [{(CF3CO2)(μ?O2CCH3)Zn}2(μ?bpe)2]n through Single?Crystal to Single?Crystal Transformation .
Toh NL, et al.
Inorganic Chemistry, 117(15), 2277-2281 (2005)
Ekaterina Babich et al.
Nanomaterials (Basel, Switzerland), 10(9) (2020-09-20)
The irradiation of silver-to-sodium ion-exchanged glass with 1.06-μm nanosecond laser pulses of mJ-range energy results in the formation of silver nanoparticles under the glass surface. Following chemical removal of ~25-nm glass layer reveals a pattern of nanoparticles capable of surface
Jun-Hui Zhang et al.
Electrophoresis, 38(19), 2513-2520 (2017-07-06)
Natural amino acids are well known to form coordination polymers with transition metal ions. In this study, six homochiral metal-organic frameworks constructed from Zn
Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption.
Maji TK, et al.
Angewandte Chemie (International Edition in English), 43(25), 3269-3272 (2004)
Isoreticular Homochiral Porous Metal- Organic Structures with Tunable Pore Sizes.
Dybtsev DN, et al.
Inorganic Chemistry, 46(17), 6843-6845 (2007)

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