B82006
2-Bromotoluene
99%
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About This Item
Linear Formula:
CH3C6H4Br
CAS Number:
Molecular Weight:
171.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-421-7
Beilstein/REAXYS Number:
1904176
MDL number:
Assay:
99%
Form:
liquid
Quality Segment
assay
99%
form
liquid
refractive index
n20/D 1.555 (lit.)
bp
58-60 °C/10 mmHg (lit.)
mp
−27 °C (lit.)
density
1.422 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
Cc1ccccc1Br
InChI
1S/C7H7Br/c1-6-4-2-3-5-7(6)8/h2-5H,1H3
InChI key
QSSXJPIWXQTSIX-UHFFFAOYSA-N
General description
2-Bromotoluene is an an electron rich heteroaryl bromide. Heck reactions of 2-bromo toluene with cycloalkene (cyclododecene) and linear alkenes (dec-1-ene, allylbenzene) catalyzed by tedicyp (cis,cis,cis -1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane)-palladium complex has been studied. Vibrational spectral analysis of 2-bromobenzene by Raman and infrared spectroscopy at 50-4000cm-1 has been investigated. Suzuki cross-coupling of 2-bromobenzene with benzeneboronic acid catalyzed by the Tedicyp-palladium complex has been studied. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported.
Application
2-Bromotoluene was used in the synthesis of (±)-isocomene.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F
flash_point_c
79 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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