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Merck
CN

D133000

3,4-Dimethoxybenzyl alcohol

96%

Synonym(s):

(3,4-Dimethoxyphenyl)methanol, Veratryl alcohol

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About This Item

Linear Formula:
(CH3O)2C6H3CH2OH
CAS Number:
93-03-8
Molecular Weight:
168.19
Beilstein/REAXYS Number:
639388
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24893258
EC Number:
202-212-0
MDL number:
MFCD00004638
Assay:
96%
Form:
liquid

Key Documents

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Product Name

3,4-Dimethoxybenzyl alcohol, 96%

assay

96%

form

liquid

InChI key

OEGPRYNGFWGMMV-UHFFFAOYSA-N

InChI

1S/C9H12O3/c1-11-8-4-3-7(6-10)5-9(8)12-2/h3-5,10H,6H2,1-2H3

SMILES string

COc1ccc(CO)cc1OC

refractive index

n20/D 1.552 (lit.)

bp

296-297 °C/732 mmHg (lit.)

density

1.157 g/mL at 25 °C (lit.)

Quality Level

100

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Application

3,4-Dimethoxybenzyl alcohol is widely used in the synthesis of various cyclotriveratrylenes (CTVs), which are cyclic molecular hosts with a cavity to accommodate guest molecules. It can also be used as a precursor in the total synthesis of salvianolic acid N.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6919
SDBB6491
STBL3753
SDBB1337
STBJ9200

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Formal total synthesis of salvianolic acid N.
Wu K, et al.
Organic & Biomolecular Chemistry (2018)
Self-assembly of dendritic crowns into chiral supramolecular spheres.
Percec V, et al.
Journal of the American Chemical Society, 131(3), 1294-1304 (2008)
Improved synthesis of functional CTVs and cryptophanes using Sc (OTf) 3 as catalyst.
Brotin T, et al.
The Journal of Organic Chemistry, 70(16), 6187-6195 (2005)
Recent advances in the chemistry of cyclotriveratrylene.
Hardie M J
Chemical Society Reviews, 39(2), 516-527 (2010)
Liang Mao et al.
Environmental science & technology, 44(7), 2599-2604 (2010-03-17)
We have demonstrated in our earlier work that a few natural and synthetic estrogens can be effectively transformed through reactions mediated by lignin peroxidase (LiP). The behaviors of such reactions are variously influenced by the presence of natural organic matter
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