D153303
5,5-Dimethyl-1,3-cyclohexanedione
95%
Synonym(s):
Dimedone, Methone
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About This Item
Linear Formula:
(CH3)2C6H6(=O)2
CAS Number:
Molecular Weight:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-804-4
Beilstein/REAXYS Number:
471489
MDL number:
Product Name
5,5-Dimethyl-1,3-cyclohexanedione, 95%
InChI key
BADXJIPKFRBFOT-UHFFFAOYSA-N
InChI
1S/C8H12O2/c1-8(2)4-6(9)3-7(10)5-8/h3-5H2,1-2H3
SMILES string
CC1(C)CC(=O)CC(=O)C1
assay
95%
form
powder
mp
146-148 °C (lit.)
Quality Level
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Related Categories
Application
Part of furannulation strategy for the synthesis of naturally occurring fused 3-methylfurans.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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The Journal of Organic Chemistry, 58, 3960-3960 (1993)
Quantification of protein sulfenic acid modifications using isotope-coded dimedone and iododimedone.
Young Ho Seo et al.
Angewandte Chemie (International ed. in English), 50(6), 1342-1345 (2011-02-04)
Open season for hunting and trapping post-translational cysteine modifications in proteins and enzymes.
Claus Jacob et al.
Chembiochem : a European journal of chemical biology, 12(6), 841-844 (2011-03-30)
Douglas S Rehder et al.
BMC biochemistry, 11, 25-25 (2010-07-03)
Cysteine sulfenic acid (Cys-SOH) plays important roles in the redox regulation of numerous proteins. As a relatively unstable posttranslational protein modification it is difficult to quantify the degree to which any particular protein is modified by Cys-SOH within a complex
Antonio Evidente et al.
Journal of natural products, 74(4), 757-763 (2011-02-24)
Sphaeropsidone and episphaeropsidone are two phytotoxic dimedone methyl ethers produced by Diplodia cupressi, the causal agent of a canker disease of cypress in the Mediterranean area. In this study, eight derivatives obtained by chemical modifications and two natural analogues were
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