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Merck
CN

D19605

1,8-Diamino-p-menthane, mixture of cis and trans isomers

technical grade, 85%

Synonym(s):

1,8-p-Menthanediamine

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About This Item

Empirical Formula (Hill Notation):
C10H22N2
CAS Number:
80-52-4
Molecular Weight:
170.30
NACRES:
NA.22
PubChem Substance ID:
24893580
UNSPSC Code:
12352100
EC Number:
201-287-7
MDL number:
MFCD00001488
Assay:
85%
Form:
liquid

Key Documents

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InChI

1S/C10H22N2/c1-9(2,11)8-4-6-10(3,12)7-5-8/h8H,4-7,11-12H2,1-3H3

InChI key

KOGSPLLRMRSADR-UHFFFAOYSA-N

SMILES string

CC(C)(N)C1CCC(C)(N)CC1

grade

technical grade

vapor pressure

10 mmHg ( 20 °C)

assay

85%

form

liquid

refractive index

n20/D 1.4805 (lit.)

bp

107-126 °C/10 mmHg (lit.)

mp

−45 °C (lit.)

density

0.914 g/mL at 25 °C (lit.)

Quality Level

100

Related Categories

Application

1,8-Diamino-p-menthane is generally used in the synthesis of various Schiff bases that are used in the preparation of coordination complexes with Cu(II), Zn(II), Cr(III), Fe(III) and Co(III) ions. It is also used as a precursor to synthesize heterocyclic Schiff base derivatives with herbicidal activity.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
0000024171
MKCF5545
0000024709
0000021708
0000021839

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High value-added application of turpentine as a potential renewable source for the synthesis of heterocyclic Schiff base derivatives of cis-1, 8-p-menthane-diamine serving as botanical herbicides.
Zhu S, et al.
Industrial Crops and Products, 115(3), 111-116 (2018)
Cr (III), Fe (III) and Co (III) complexes of tetradentate (ONNO) Schiff base ligands: synthesis, characterization, properties and biological activity.
Keskio?lu E, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 70(3), 634-640 (2008)
Copper (II) and zinc (II) complexes of thiophene/furan carboxamides: synthesis, structure and properties.
Gunduzalp AB and Erk B
Russian Journal of Inorganic Chemistry, 55(7), 1094-1102 (2010)

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