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Merck
CN

D19605

1,8-Diamino-p-menthane, mixture of cis and trans isomers

technical grade, 85%

Synonym(s):

1,8-p-Menthanediamine

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About This Item

Empirical Formula (Hill Notation):
C10H22N2
CAS Number:
80-52-4
Molecular Weight:
170.30
EC Number:
201-287-7
MDL number:
MFCD00001488
UNSPSC Code:
12352100
PubChem Substance ID:
24893580
NACRES:
NA.22

Key Documents

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grade

technical grade

Quality Level

100

vapor pressure

10 mmHg ( 20 °C)

Assay

85%

form

liquid

refractive index

n20/D 1.4805 (lit.)

bp

107-126 °C/10 mmHg (lit.)

mp

−45 °C (lit.)

density

0.914 g/mL at 25 °C (lit.)

SMILES string

CC(C)(N)C1CCC(C)(N)CC1

InChI

1S/C10H22N2/c1-9(2,11)8-4-6-10(3,12)7-5-8/h8H,4-7,11-12H2,1-3H3

InChI key

KOGSPLLRMRSADR-UHFFFAOYSA-N

Application

1,8-Diamino-p-menthane is generally used in the synthesis of various Schiff bases that are used in the preparation of coordination complexes with Cu(II), Zn(II), Cr(III), Fe(III) and Co(III) ions. It is also used as a precursor to synthesize heterocyclic Schiff base derivatives with herbicidal activity.

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301 + H311 + H331,H314

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Skin Corr. 1B

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

199.4 °F - closed cup

Flash Point(C)

93 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000024171
MKCF5545
0000024709
0000021708
0000021839

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Copper (II) and zinc (II) complexes of thiophene/furan carboxamides: synthesis, structure and properties.
Gunduzalp AB and Erk B
Russian Journal of Inorganic Chemistry, 55(7), 1094-1102 (2010)
Cr (III), Fe (III) and Co (III) complexes of tetradentate (ONNO) Schiff base ligands: synthesis, characterization, properties and biological activity.
Keskio?lu E, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 70(3), 634-640 (2008)
High value-added application of turpentine as a potential renewable source for the synthesis of heterocyclic Schiff base derivatives of cis-1, 8-p-menthane-diamine serving as botanical herbicides.
Zhu S, et al.
Industrial Crops and Products, 115(3), 111-116 (2018)

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