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Merck
CN

D38308

2,4′-Dibromoacetophenone

>98%

Synonym(s):

4′-Bromophenacyl bromide

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About This Item

Linear Formula:
BrC6H4COCH2Br
CAS Number:
99-73-0
Molecular Weight:
277.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24893785
EC Number:
202-783-6
Beilstein/REAXYS Number:
607604
MDL number:
MFCD00000200
Assay:
>98%
Form:
crystals

Key Documents

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InChI key

FKJSFKCZZIXQIP-UHFFFAOYSA-N

InChI

1S/C8H6Br2O/c9-5-8(11)6-1-3-7(10)4-2-6/h1-4H,5H2

SMILES string

BrCC(=O)c1ccc(Br)cc1

assay

>98%

form

crystals

mp

108-110 °C (lit.)

Quality Level

200

Gene Information

human ... PLA2G2A(5320)
rat ... Pla2g2a(29692)

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Application

Undergoes condensation reactions with aldehydes in the presence of SnCl2 or SmI3 to afford α,β-unsaturated ketones. Also useful in the esterification of carboxylic acids.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCP4204
BCCN4713
BCCK4052
BCCG5837
BCCD0381

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Tetrahedron, 49, 9735-9735 (1993)
Synthetic Communications, 23, 271-271 (1993)
Tetrahedron Letters, 34, 4547-4547 (1993)
Wen-Hsin Liu et al.
Toxicology letters, 185(2), 102-109 (2009-01-03)
In view of the controversial role of catalytic activity on the cytotoxicity of phospholipase A(2) (PLA(2)), the present study is conducted to explore whether PLA(2) induces apoptotic process of human leukemia U937 cells through catalytic activity-independent pathway. Modification of His-48
D P Marchi-Salvador et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 62(Pt 6), 600-603 (2006-06-07)
For the first time, a non-catalytic and myotoxic Lys49-PLA2 (BthTX-I from Bothrops jararacussu venom) has been crystallized with BPB inhibitor. X-ray diffraction data were collected and electron-density calculations showed that the ligand is bound to the His48 residue. BthTX-I with
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