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Merck
CN

D91209

Diethyl bromomalonate

92%

Synonym(s):

α-Bromomalonic ester, 1,3-Diethyl 2-bromopropanedioate, 2-Bromomalonic acid diethyl ester, Bromomalonic acid diethyl ester, Diethyl α-bromomalonate, Diethyl 2-bromo-1,3-propanedioate, Diethyl 2-bromomalonate, Diethyl 2-bromopropanedioate, Diethyl bromopropanedioate, Ethyl bromomalonate

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About This Item

Linear Formula:
BrCH(CO2CH2CH3)2
CAS Number:
685-87-0
Molecular Weight:
239.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24894253
EC Number:
211-683-1
Beilstein/REAXYS Number:
509768
MDL number:
MFCD00009138

Key Documents

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Product Name

Diethyl bromomalonate, 92%

InChI

1S/C7H11BrO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3

InChI key

FNJVDWXUKLTFFL-UHFFFAOYSA-N

SMILES string

CCOC(=O)C(Br)C(=O)OCC

assay

92%

form

liquid

refractive index

n20/D 1.451 (lit.)

bp

233-235 °C (lit.)

density

1.402 g/mL at 25 °C (lit.)

Quality Level

100

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Other Notes

Contains diethyl dibromomalonate, and varying amounts of diethyl malonate

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

231.8 °F - closed cup

flash_point_c

111 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC5340
BCCC2516
0000022588
BCBS6878V
BCBL9452V

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Joanna Kujawa et al.
Polymers, 11(7) (2019-07-25)
1-(1,3-diethoxy-1,3-dioxopropan-2-ylo)-3-methylimidazolium bromide (RIL1_Br), 1-(2-etoxy-2-oxoethyl)-3-methylimidazolium bromide (RIL2_Br), 1-(2-etoxy-2-oxoethyl)-3-methylimidazolium tetrafluoroborate (RIL3_BF4) ionic liquids were synthesized. Subsequently, the dense cellulose acetate propionate (CAP)-based materials containing from 9 to 28.6 wt % of these reactive ionic liquids were elaborated. Reactive ionic liquids (RILs) were
Jinjin Shi et al.
International journal of nanomedicine, 8, 1551-1562 (2013-05-03)
Fullerene (C60) has shown great potential in drug delivery. In this study we exploited modified fullerene (diadduct malonic acid-fullerene-Asn-Gly-Arg peptide [DMA-C60-NGR]) as an antitumor drug carrier in order to build a new tumor-targeting drug delivery system. We also investigated the
Shefang Ye et al.
Nanoscale research letters, 10(1), 953-953 (2015-06-11)
Fullerene (C60) derivatives, a unique class of compounds with potent antioxidant properties, have been reported to exert a wide variety of biological activities including neuroprotective properties. Mitochondrial dynamics are an important constituent of cellular quality control and function, and an

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